Quantum effects in the capture of charged particles by dipolar polarizable symmetric top molecules. II. Interplay between electrostatic and gyroscopic interactions.

نویسندگان

  • M Auzinsh
  • E I Dashevskaya
  • I Litvin
  • E E Nikitin
  • J Troe
چکیده

Within the general axially nonadiabatic channel approach described in Paper I of this series [M. Auzinsh, E. I. Dashevskaya, I. Litvin, E. E. Nikitin, and J. Troe, J. Chem. Phys. 139, 084311 (2013)], the present article analyzes the simultaneous manifestation of electrostatic and gyroscopic interactions in the quantum capture of dipolar polarizable symmetric top molecules by ions. As a demonstration, the rate coefficients for capture of CH3D and CD3H by H(+), D(+), and H3(+) are calculated.

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عنوان ژورنال:
  • The Journal of chemical physics

دوره 139 14  شماره 

صفحات  -

تاریخ انتشار 2013